Magmatic Evolution and Rare Metal Mineralization in Mount El-Sibai Peralkaline Granites, Central Eastern Desert, Egypt: Insights from Whole-Rock Geochemistry and Mineral Chemistry Data

The Ediacaran peralkaline granites, which were emplaced during the post-collisional tectonic extensional stage, have a limited occurrence in the northern tip of the Nubian Shield. In this contribution, we present new mineralogical and geochemical data of Mount El-Sibai granites from the Central Eastern Desert of Egypt. The aim is to discuss their crystallization condition, tectonic setting, and petrogenesis as well as the magmatic evolution of their associated mineralization. Mount El-Sibai consists of alkali-feldspar granites (AFGs) as a main rock unit with scattered and small occurrences of alkali-amphibole granites (AAGs) at the periphery. The AAG contain columbite, nioboaeschynite, zircon and thorite as important rare metal-bearing minerals. Geochemically, both of AFG and AAG exhibit a highly evolved nature with a typical peralkaline composition (A/CNK = 0.82–0.97) and formed in within-plate anorogenic setting associated with crustal extension and/or rifting. They are enriched in some LILEs (Rb, K, and Th) and HFSEs (Ta, Pb, Zr, and Y), but strongly depleted in Ba, Sr, P and Ti with pronounced negative Eu anomalies (Eu/Eu* = 0.07–0.34), consistent with an A-type granite geochemical signature. The calculated TZrn (774–878 °C) temperatures indicate that the magma was significantly hot, promoting the saturation of zircon. The texture and chemistry of minerals suggest that they were crystallized directly from a granitic magma and were later subject to late- to post-magmatic fluids. Both granitic types were most likely generated through partial melting of a juvenile crustal source followed by magmatic fractionation. The lithospheric delamination is the main mechanism which causes uplifting of the asthenospheric melts and hence provides enough heat for crustal melting. The produced parent magma was subjected to prolonged fractional crystallization to produce the different types of Mount El-Sibai granites at different shallow crustal levels. During magma fractionation, the post-magmatic fluids (especially fluorine) contribute significantly to the formation of rare metal mineralization within Mount El-Sibai granites

Landslide Susceptibility Assessment of a Part of the Western Ghats (India) Employing the AHP and F-AHP Models and Comparison with Existing Susceptibility Maps

Landslides are prevalent in the Western Ghats, and the incidences that happened in 2021 in the Koottickal area of the Kottayam district (Western Ghats) resulted in the loss of 10 lives. The objectives of this study are to assess the landslide susceptibility of the high-range local self-governments (LSGs) in the Kottayam district using the analytical hierarchy process (AHP) and fuzzy-AHP (F-AHP) models and to compare the performance of existing landslide susceptible maps. This area never witnessed any massive landslides of this dimension, which warrants the necessity of relooking into the existing landslide-susceptible models. For AHP and F-AHP modeling, ten conditioning factors were selected: slope, soil texture, land use/land cover (LULC), geomorphology, road buffer, lithology, and satellite image-derived indices such as the normalized difference road landslide index (NDRLI), the normalized difference water index (NDWI), the normalized burn ratio (NBR), and the soil-adjusted vegetation index (SAVI). The landslide-susceptible zones were categorized into three: low, moderate, and high. The validation of the maps created using the receiver operating characteristic (ROC) technique ascertained the performances of the AHP, F-AHP, and TISSA maps as excellent, with an area under the ROC curve (AUC) value above 0.80, and the NCESS map as acceptable, with an AUC value above 0.70. Though the difference is negligible, the map prepared using the TISSA model has better performance (AUC = 0.889) than the F-AHP (AUC = 0.872), AHP (AUC = 0.867), and NCESS (AUC = 0.789) models. The validation of maps employing other matrices such as accuracy, mean absolute error (MAE), and root mean square error (RMSE) also confirmed that the TISSA model (0.869, 0.226, and 0.122, respectively) has better performance, followed by the F-AHP (0.856, 0.243, and 0.147, respectively), AHP (0.855, 0.249, and 0.159, respectively), and NCESS (0.770, 0.309, and 0.177, respectively) models. The most landslide-inducing factors in this area that were identified through this study are slope, soil texture, LULC, geomorphology, and NDRLI. Koottickal, Poonjar-Thekkekara, Moonnilavu, Thalanad, and Koruthodu are the LSGs that are highly susceptible to landslides. The identification of landslide-susceptible areas using diversified techniques will aid decision-makers in identifying critical infrastructure at risk and alternate routes for emergency evacuation of people to safer terrain during an exigency

The contribution of outdoor air pollution sources to premature mortality on a global scale

Assessment of the global burden of disease is based on epidemiological cohort studies that connect premature mortality to a wide range of causes, including the long-term health impacts of ozone and fine particulate matter with a diameter smaller than 2.5 micrometres (PM2.5). It has proved difficult to quantify premature mortality related to air pollution, notably in regions where air quality is not monitored, and also because the toxicity of particles from various sources may vary. Here we use a global atmospheric chemistry model to investigate the link between premature mortality and seven emission source categories in urban and rural environments. In accord with the global burden of disease for 2010 (ref. 5), we calculate that outdoor air pollution, mostly by PM2.5, leads to 3.3 (95 per cent confidence interval 1.61-4.81) million premature deaths per year worldwide, predominantly in Asia. We primarily assume that all particles are equally toxic, but also include a sensitivity study that accounts for differential toxicity. We find that emissions from residential energy use such as heating and cooking, prevalent in India and China, have the largest impact on premature mortality globally, being even more dominant if carbonaceous particles are assumed to be most toxic. Whereas in much of the USA and in a few other countries emissions from traffic and power generation are important, in eastern USA, Europe, Russia and East Asia agricultural emissions make the largest relative contribution to PM2.5, with the estimate of overall health impact depending on assumptions regarding particle toxicity. Model projections based on a business-as-usual emission scenario indicate that the contribution of outdoor air pollution to premature mortality could double by 2050

Oxygen and hydrogen stable isotopes as recharge indicators, Central Nile Delta Quaternary aquifer, Egypt

This work aims to utilize oxygen and hydrogen stable isotopes as tracers for determining the groundwater sources of recharge in the central Nile delta. The analyzed water samples were collected from canals and drains as surface water, soil water and shallow, intermediate and deep zones of the groundwater. The isotopic data indicated that surface water samples have higher isotopic content than recent Nile river water (&#948 18O = 2.39‰ and &#9482 H = 22‰) which reflect the influence of an evaporation process that takes place in surface water bodies during its flow. Soil water samples were affected by evaporation process during water infiltration via soil. It was estimated that soil water samples have higher enrichment isotopic contents than groundwater and less than surface and recent Nile water. Studied groundwater is composed of mixed source from groundwater recharged before and that recharged after High Dam construction. Few groundwater samples have depleted isotopic content which suggested a mixing source between the rainwater and the Nile River water before High Dam construction. The evaporation is indicated in the shallow groundwater by the deviation away from the global meteoric line. In the deep groundwater, more deviation from global meteoric line was noticed which reflects the effect of mixing between freshwater and seawater. The intermediate groundwater samples average line showed an intermediate deviation indicating the effect of both evaporation and seawater intrusion

Using Airborne Geophysical and Geochemical Methods to Map Structures and Their Related Gold Mineralization

Egypt’s mineral resources are an effective means of raising the country’s income. Consequently, searching for deep subsurface ore deposits is essential. In this study, we map the subsurface structure and the occurrence of related gold-ore mineralization deposits in ophiolitic-assemblage rocks around the Wadi El-Saqia area in the Central Eastern Desert of Egypt. Our approach combines airborne geophysical data (aeromagnetic mapping) and geochemical analyses. We enhanced the aeromagnetic data and interpreted them using edge-detection methods, such as the first-order vertical derivative (FVD), the analytic signal (AS), the total horizontal derivative (THD), the tilt derivative (TD), the tilt angle (TA), the theta map, both grid and porphyry analyses from the Centre for Exploration Targeting (CET), and Euler deconvolution (ED) techniques. Utilizing these methods, we located the main structural lineaments/contacts that control the distribution of hydrothermal alteration zones. In addition, our geochemical analyses use the mineral chemistry of pyroxene and plagioclase to describe their tectonic and magmatic evolution. The airborne geophysical results revealed that NW–SE, NE–SW, N–S, and E–W structural orientations are prevalent in the studied area, with depths ranging from less than 50 m to about 600 m. To validate the findings, we carried out geochemical sampling, which indicates that pyrite, galena, pyrrhotite, and electrum contain good percentages of gold (ranging from 0.01–0.09 wt%, 0.03–0.1 wt%, 0.12–0.14 wt%, and 53.55–55.01 wt%, respectively). In this study, we were thus able to find preferred locations for gold mineralization, which highlights the value of combining aeromagnetic and geochemical data for mineral exploration

Analysis of the shoreline changes using geoinformatics in Ghoramara Island of Hugli Estuary, West Bengal in India

Conceptual Framework: Coastal decrepitude is the loss of topographical resources along the coast as a result of silt, temperature fluctuations, tidal shifts, and wave breaking. Hydraulic activity, scraping, abrasion, and erosion are the major causes of erosion; other factors that affect it include the condition of the shore, rocks, joints, fissures, marine chemical reactions, and wave force. Objectives: The primary objectives of this study are to analyze the coastline changes between 1972 and 2022 utilizing remote sensing and GIS data and forecast the changes in the shoreline in 2032. Methods: The study examined coastal areas from 1972 to 2022 using multi-temporal satellite data from Landsat TM and Landsat OLI/TIRS. Shoreline change and the calculations related to it were examined using the Digital Shoreline Analysis System using near-infrared bands and tasseled cap transformation, to determine the rate of change in the shoreline, the study also employed Shoreline Change Envelope and End Point Rate techniques. Results: Coastal erosion caused substantial damage to the island between 1972 and 2022. The northern, southeastern, and western regions of the coast are seeing the highest levels of coastal erosion. The south coast experiences considerable erosion, whereas the west and southeast coasts experience the least. The EPR of Ghoramara Island has mean, minimum, and maximum changes of −10.59, −4.13, and −35.93, respectively. A notable inshore shift has occurred in the northern portion of Ghoramara, extending from 676 m to 855 m. The study also uses tidal gauge records and Revised Local Reference data from the Haldia Gauge Station to track long-term sea level variations. According to the study, Ghoramara Island's shoreline will change by 2032, with the greatest negative changes expected to occur around the island's western and southern borders. Conclusion: The study shows a significant decrease in Ghoramara's shoreline regions between 1972 and 2022, with a 3,000-population shifted from the place in 2016 due to Lohachara's submergence. Changes in the island's morphology and human activities have reduced cultivation. The study suggests increasing mangrove vegetation to combat coastal erosion and prevent further displacement of people to neighboring islands

Application of GIS, Multi-Criteria Decision-Making Techniques for Mapping Groundwater Potential Zones: A Case Study of Thalawa Division, Sri Lanka

Groundwater resources are depleting due to phenomena such as significant climate change and overexploitation. Therefore, it is essential to estimate water production and identify potential groundwater zones. An integrated conceptual framework comprising GIS and the analytical hierarchy process (AHP) has been applied for the present study to identify groundwater potential areas in the Thalawa division of Sri Lanka. The criteria, including rainfall, soil types, slope, stream density, lineament density, geology, geomorphology, and land use, were taken into account as the most contributing factors when identifying the groundwater zones. Weights were allocated proportionally to the eight thematic layers according to their importance. Hierarchical ranking and final normalized weighting of these determinants were performed using the pairwise comparison matrix (PCM) available in AHP. Based on the results obtained, the groundwater potential zone (GWPZ) was classified into three regions: low potentiality (33.4%), moderate potentiality (55.8%), and high potentiality (10.6%). Finally, the zoning map was compared to find consistency with field data on groundwater discharge and depth taken from 18 wells in the division. The results revealed that the GIS-multi-criteria decision-making (MCDM) approach brings about noticeably better results, which can support groundwater resource planning and sustainable use in the research area

Application of Analytical Hierarchy Process and Geophysical Method for Groundwater Potential Mapping in the Tata Basin, Morocco

Ensuring water availability for agriculture and drinking water supply in semi-arid mountainous regions requires control of factors influencing groundwater availability. In most cases, the population draws its water needs from the alluvial aquifers close to villages that are already limited and influenced by current climatic change. In addition, the establishment of deep wells in the hard rock aquifers depletes the aquifer. Hence, understanding the factors influencing water availability is an urgent requirement. The use of geographic information system (GIS), and remote sensing (RS), together with decision-making methods like analytical hierarchy process (AHP) will be of good aid in this regard. In the Tata basin, located in SE Morocco, ten factors were used to explain the groundwater potentiality map (GWPM). Five categories of potential zones were determined: very low (8.67%), low (17.74%), moderate (46.77%), high (19.95%), and very high (6.87%). The efficiency of the AHP model is validated using the ROC curve (receiver operating characteristics) which revealed a good correlation between the high potential groundwater zones and the spatial distribution of high flow wells. Geophysical prospecting, using electrical resistivity profiles, has made it possible to propose new well sites. It corresponds to conductive resistivity zones that coincide with the intersection of hydrogeological lineaments

Application of Fuzzy Logic and Fractal Modeling Approach for Groundwater Potential Mapping in Semi-Arid Akka Basin, Southeast Morocco

Groundwater potential delineation in the Akka basin, southwest Morocco, has been determined through the combination of geospatial techniques and geological data. The geometric average and expected value are two multi-criteria approaches used to integrate a set of factors–data for which the weights of each factor are assigned using the fuzzy logic function, which transforms values of factors influencing groundwater presence in a range of [0, 1]. The efficiency factors used in this study are the lineament density, node density, drainage density, distance from rivers, distance from lineament, permeability, slope, topographic witness index, plan curvature, and profile curvature. Thereafter, the groundwater potential map was generated in a GIS environment. To assess and compare the efficiency of the two models, the well data existing in the basin were used to choose the most efficient model. For that reason, the prediction area (P–A) graph, the normalized density (Nd), and its weight (We) were applied to estimate the capacity of each model to predict the target area. The analysis shows that the expected value model (Nd = 1.86 and We = 0.62) is more efficient than the geometric average model (Nd = 0.96 and We = −0.04). The results of the expected value model can be used in the future planning and management of water resources in the Akka basin

A Multidisciplinary Approach for Groundwater Potential Mapping in a Fractured Semi-Arid Terrain (Kerdous Inlier, Western Anti-Atlas, Morocco)

This study is focused on developing an approach for spatial mapping of groundwater by considering four types of factors (geological, topographical, hydrological, and climatic factors), and by using different bivariate statistical models, such as frequency ratio (FR) and Shannon’s entropy (SE). The developed approach was applied in a fractured aquifer basin (Ameln Basin, Western Anti-Atlas, Morocco), to map the spatial variation of groundwater potential. Fifteen factors (15) influencing groundwater were considered in this study, including slope degree, slope aspect, elevation, topographic wetness index (TWI), slope length (LS), topographic position index (TPI), plane curvature, profile curvature, drainage density, lineament density, distance to rivers and fault network, normalized difference vegetation index (NDVI), lithology, and land surface temperature (LST). The potential maps produced were then classified into five classes to illustrate the spatial view of each potential class obtained. The predictive capacity of the frequency ratio and Shannon’s entropy models was determined using two different methods, the first one based on the use of flow data from 49 boreholes drilled in the study area, to test and statistically calibrate the predictive capacity of each model. The results show that the percentage of positive water points corresponds to the most productive areas (high water flow) (42.86% and 30.61% for the FR and SE models, respectively). On the other hand, the low water flows are consistent with the predicted unfavorable areas for hydrogeological prospecting (4.08% for the FR model and 6.12% for the SE model). Additionally, the second validation method involves the integration of 7200 Hz apparent resistivity data to identify conductive zones that are groundwater circulation zones. The interpretation of the geophysical results shows that the high-potential zones match with low apparent resistivity zones, and therefore promising targets for hydrogeological investigation. The FR and SE models have proved very efficient for hydrogeological mapping at a fractured basement area and suggest that the northern and southern part of the study area, specifically the two major fault zones (Ameln Valley in the north, and the Tighmi-Tifermit Valley in the south) has an adequate availability of groundwater, whereas the central part, covering the localities of Tarçouat, Boutabi, Tililan, and Ighalen, presents a scarcity of groundwater. The trend histogram of the evolution of positive water points according to each potentiality class obtained suggests that the FR model was more accurate than the SE model in predicting the potential groundwater areas. The results suggest that the proposed approach is very important for hydrogeological mapping of fractured aquifers, and the resulting maps can be helpful to managers and planners to generate groundwater development plans and attenuate the consequences of future drought